Phenanthroline相关论文
Improved phenanthroline photospectrometry for simutaneous determination of Fe(Ⅱ)and Fe(Ⅲ)in bioleach
An inproved phenanthroline (PNT) photospectrometry for simutaneous determination of Fe(Ⅱ) and Fe(Ⅲ) in bioleaching sam......
Synthesis and the Interaction of 2-(1H-pyrazol-4-yl)-1H-imidazo[4,5-f][1,10]phenanthrolines with Tel
A novel series of 2-(1H-pyrazol-4-yl)-1H-imidazo[4,5-f][1,10]phenanthrolines were designed,synthesized and evaluated for......
Single Copper(Ⅰ)Complexes Based on Phenanthroline derivatives P^N^N^P Tetradentate Ligands:Syntheses
Two novel heteroleptic Cu(Ⅰ)complexes with the single tetradentate ligands have been designed and synthesized from phen......
The host-guest relationship between cucurbit[8]uril, phenanthrolines and some methyl substituted 1,10-phenanthrolines ha......
Synthesis,Crystal Structure and DNA Interaction of a Chiral Platinum(Ⅱ) Complex with 2-(2,3-Dimethox
A new platinum(Ⅱ) complex of [Pt(chda)(2,3-dmopip)]Cl·H_2O(1, chda = cyclohexan-ediamine, 2,3-dmopipH = 2-(2,3-dimetho......
MnCl2 (C12,H8N2)2, Mr= 486. 26, monoclinic, P21,/c, a= 9. 461 (5),b= 15. 20(1), c= 14. 514(2) A, β=98. 82(3)°, V=2062(......
Synthesis, Characterization and Fluorescence Studies on Complexes of Terbium with Phenylglyoxylic Ac
Three new complexes TbL_3dipy(H_2O)_2, TbL_3phen(H_2O)_2 and TbL_2(TPPO)_2NO_3 have been synthesized (L=phenylglyoxylate......
Hydrothermal Synthesis and Crystal Structure of a Zinc Complex:[Zn_(2.5)(phen)(BDC)_2(OH)] (phen = 1
A metal-organic coordination polymer [Zn2.5(phen)(BDC)2(OH)]2 (phen = 1,10- phenanthroline, BDC = benzene-1,4-dicarboxyl......
Synthesis and Crystal Structure of an Adipate-bridged Dinuclear Cadmium(Ⅱ)Polymer with 2-Methylpyraz
A metal-organic coordination polymer,[Cd(C_(15)H_(10)N_4)(C_6H_8O_4)]_(2n)(1,C_(15)H_(10)N_4: 2-methyl-pyrazino-[2,3-f][......
Synthesis and characterization of terbium(Ⅲ)-pyromellitic acid(H_4L)-1,10-phenanthroline (phen) lumi
The terbium(Ⅲ)-pyromellitic acid(H4L)-1,10-phenanthroline(phen) luminescent complex was synthesized using a co-precipit......
采用不同尺寸的高荧光量子产率、单分散性水溶性CdTe量子点(QDs)与菲啰啉(Phen)配体结合,组装成QDs-Phen荧光探针。Phen对不同尺寸......
以邻菲啰啉为显色剂,采用紫外-可见分光光度计测定Fe-NTA体系中全铁、Fe~(2+)、Fe~(3+)的浓度。分别考察了FeNTA脱硫液中的络合比......
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设计并制备具不同官能团的钌(Ⅱ)邻菲啰啉配合物——[Ru(bpy)2(phen-NO2)](PF6)2(1),[Ru(bpy)2(phen-Br)](PF6)2(2),[Ru(bpy)2(phe......
本文通过对荣华二采区10...
本文通过对荣华二采区10...
Synthesis, Crystal Structure and DNA Interaction of a Chiral Platinum(Ⅱ) Complex with 2-(2,3-Dimetho
本文通过对荣华二采区10...
Synthesis, luminescent properties, and theoretical study of novel Sm3+ and Dy3+ complexes containing
Two new tary complexes of 1-(2-thienyl)-3-(p-phenylethynylphenyl)-1,3-propanedione (HTPP) and 1,10-phenanthroline (phen)......
Two New Coordination Polymers: [M(phen)(e, a-cis-1, 4-chdc)(H2O)]n (M=Mn and Cu;phen=1, 10-phenanthr
Two new coordination polymers, [M(phen) (e, a-cis-1, 4-chdc) (H2O) ] n (M=Mn(1);M=Cu(2);chdc=cyclohexanedicarboxylic aci......
Efficient Synthesis of Complex Bridged 1,3-Oxazabicycles via Reactions of N-Alkyl-1,10-phenanthrolin
本文通过对荣华二采区10...
Diastereoselective Synthesis of 1,10-Dihydropyrrolo [1,2-a] [1,10]phenanthroline Derivatives via 1,3
本文通过对荣华二采区10...
Efficient Synthesis of Complex Bridged 1,3-Oxazabicycles via Reactions of N-Alkyl-1,10-phenanthrolin
Complex bridged 1,3-oxazabicycles and 1,4-disubstituted 1,10-phenanthroline derivatives were efficiently prepared by the......
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
Two New Coordination Polymers: [M(phen)(e, a-cis-1, 4-chdc)(H2O)]n (M=Mn and Cu;phen=1, 10-phenanthr
Two new coordination polymers, [M(phen) (e, a-cis-1, 4-chdc) (H2O) ] n (M=Mn(1);M=Cu(2);chdc=cyclohexanedicarboxylic aci......
In biological systems, monooxygenase, exemplified by cytochrome P-450, can efficiently catalyze hydroxylation and epoxid......
In this paper, we present the synthesis and anion recognition properties of the amide based phenanthroline derivatives 1......
Diethyl carbonate (DEC) is one of the important green chemicals widely used for organic synthesis because of its various......
The host-guest relationship between cucurbit[8]uril, phenanthrolines and some methyl substituted 1,10-phenanthrolines ha......
Synthesis, EPR and Fluorescence Properties of Quaternary Lanthanide Complexes with Chloroacetate and
A series of novel quaternary mixed anion complexes of lanthanide containing 1,10-phenanthroline (phen) and chloroacetate......
测定了ＶＯＳＯ４与蛋氨酸及ＶＯＳＯ４与蛋氨酸、各啉在不同酸度的乙二醇／水（１：１）溶液中的低温ＥＰＲ波谱，发现在不同ＰＨ下生成不同组成、结构的配合物，利用Ｊｏｈｎｓｏｎ加合规则并结......
双羰化是制备α-酮酸及其衍生物的重要反应,因其反应途径简捷且收率高而倍受青睐,国内外有不少关于氯苄双羰化合成苯丙酮酸的报道.......
通过Ｔｙｎｄａｌｌ效应，电镜观察和超过滤实验，发现ＦｅＣｌ３－Ａｌ（ｉ－Ｂｕ）３－Ｐｈｅｎ，催化剂在溶有丁二烯的加氢汽油介质中为胶体分散系，活性中心位于胶体催化剂的胶粒表面，催化剂各组......
本文对镉(Ⅱ)——邻菲啰啉配合物的极谱行为进行了研究,提出了单扫示波极谱法测定痕量镉的新方法。在0.25mol·1~(-1)的Na_2CO......
邻菲咯啉是一种二肽酶抑制剂。本试验用体外法测定了不同浓度邻菲咯啉对瘤胃微生物发酵产气量、氨氮浓度、真蛋白含量及饲料干物质......
合成了6种稀土(RE)-萘乙酸(NAA)-邻菲绕啉(Phen)固体配合物,其通式为RE(NAA)_3·Phen(RE=Y,La,Nd,Sm,Eu,Er)。通过元素分析,摩......
测定了ＶＯＳＯ４与谷氨酸及ＶＯＳＯ４与谷氨酸，１，１０－邻菲咯啉在乙二醇／水（１：１）溶液中的低温ＥＳＲ波谱，利用Ｊｏｈｎｓｏｎ加和规则并结合ＩＲ，推测了在不同ＰＨ下生成的配合物的可能结构，利用电子......
用Ｈ ＮＭＲ法研究了钯（ＩＩ）混配物子内芳环配体间的堆积作用，结果表明堆积度和参与堆积的芳环大小一致。......
4-酰代双吡唑酮是一类非环四齿β-二酮螯合剂.我们合成了双-（1′-苯基-3′-甲基-5′-氧代吡唑-4′-基）乙二酮（H<sub>2</sub>BPMPED,简......
制备了铬（Ⅲ）邻菲咯啉，８－羟基喹啉配合物／Ｙ型分子筛，利用元素分析，ＳＥＭ，ＵＶ－ＶｉｓＢＥＴ及ＸＲＤ等方法确定了分子筛选笼中金属配合物的生在及其晶体结构，考察了实验参数......
报道了１４种稀土元素与异烟酸（ＨＬ）邻菲咯啉（Ｐｈｅｎ）形成的三元固体配合物的制备方法，通过元素分析和化学分析确定了配合物的化学组成为ＲＥ（Ｐｈｅｎ）Ｌ３，并利用ＩＲ，ＵＶ，＾１ＨＮＭＲ，荧光光......
提出了用草酸-邻菲啰啉去除硅灰石中Fe2+的方法,研究了浸取剂的浓度、浸取时间和温度等条件对Fe2+的去除率的影响,在最佳的浸取条......
采用水溶液合成法,合成了新型配合物[Dy（p-MBA）3phen]2（p-MBA=对甲基苯甲酸;phen=1,10-邻菲啰啉）。通过元素分析、红外光谱、摩尔电导......
合成了稀土（Ｌｎ）与２，２－联吡啶（Ｌ１）、１，１０－菲罗啉（Ｌ２）的三元固态配合物。通过元素分析、ＩＲ谱、ＴＧＡ谱和摩尔电导等对该系列配合物进行了表征，实测结果与通式ＬｎＬ１Ｌ２Ｃｌ３·......
以金属钴（Ⅱ）盐与L-磺基丙氨酸和邻菲咯咻配体合成了三元配合物[CoL （phen）2]H2O （L=L-磺基丙氨酸,phen=邻菲咯啉）,并对其进行红外光谱和......
采用自由配体法,将铁邻菲啰啉（Fe（phen）3）配合物封装在含有不同碱金属阳离子的Y型分子筛中,制备了系列Fe（phen）3/M-Y（M=Li^＋,Na^＋,K^＋和Cs^＋）催......
以1,10-菲咯啉为原料经过三步反应合成得到5,6-二胺-1,10-菲咯啉，常温下5,6-二胺-1,10-菲咯啉与苯偶酰反应生成目标产物2,3-二苯基......
根据镍对邻菲罗啉的荧光具有猝灭的特性,拟定了一种测定痕量镍的新方法.体系的最大激发波长为225 nm,最大发射波长为360 nm;该方法......
合成了两个单酚钠的邻菲罗啉配合物和两个桥联二酚钠的邻菲罗啉配合物,通过X光单晶衍射测定了它们的晶体结构。2,6-二叔丁基-4-甲......
